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Sodium Carboxymethyl Cellulose

 

Sodium CMC is Cellulose ether produced by reacting Cellulose with caustic soda and monochloroacetic acid in presence of alcohol under rigidly controlled conditions.

CASRN: 9004-32-4

CAS Name: Cellulose, Carboxymethyl ether, Sodium

Structure of cellulose

Cellulose is a water-insoluble polymer of vegetable origin such as wood (eucalyptus, poplar, pine) or cotton. The cellulose molecule consists of a large number of glucose anhydride rings linked in chain formation. Each polymer chain consists of 100 to 6000 glucose anhydride units

Structure of Sodium CMC

Chemical Reaction Process Description: Sodium Carboxymethyl Cellulose is generally produced by the reaction of Monochloroacetic acid (or it’s Sodium Salt) with alkali cellulose prepared by treating Pulp with caustic soda 50% aqueous solution.

CellOH + NaOH-------------------CelloNa + H2O
Cellulose+ Caustic soda-----------alkali cellulose+ water

ClCH2COOH + NaOH---------------- ClCH2COONa +H2O
MCA+ caustic soda---------sodium MCA+ Water
CellONa + ClCH2COONa ------CellOCH2COONa (Sodium CMC)

 

 
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